Chemists have developed a novel way to capture and convert carbon dioxide into methane, suggesting that future gas emissions could be converted into an alternative fuel using electricity from renewable sources.
Carbon dioxide (CO2) is a greenhouse gas that accounts for a large part of Earth's warming climate, and is produced by power plants, factories and various forms of transportation. Typical carbon capture systems aimed at reducing its presence in the atmosphere work to lower carbon dioxide emissions by isolating CO2 from other gases and converting it to useful products. However, this process is difficult to implement on an industrial scale due to the massive amount of energy required for these systems to operate.
Now, using a special nickel-based catalyst, researchers have figured out a way to save much of this precious energy by turning captured carbon dioxide directly into methane, said Tomaz Neves-Garcia, lead author of the study and a current postdoctoral researcher in chemistry and biochemistry at The Ohio State University.
By employing nickel atoms laid out on an electrified surface, the team was able to directly convert carbamate, the captured form of carbon dioxide, to methane. They found that nickel atoms, a cheap and widely available catalyst, were extremely good at making this conversion.
Most importantly, streamlining the carbon capture process helps reframe what scientists know about the carbon cycle, and is a vital step to setting up more complex strategies for faster and more efficient climate mitigation technologies.
The paper was recently published in the Journal of the American Chemical Society.
Although many carbon capture methods are still in their early stages, with researchers from an array of fields working to improve them, the field is a promising one, said Neves-Garcia.
Converting CO2 into a fuel using renewable electricity has the potential to close the carbon cycle. For example, when methane is burned to generate energy, it emits carbon dioxide, which, if captured and converted back to methane, could lead to a continuous cycle of energy production without adding to Earth's global warming burden.